In wet corrosion conditions, it is rarely possible to use coatings with noble metals that do not corrode, for economic reasons.
One of the most widely used methods is cathodic protection, which is generally inexpensive and effective over a long period of time when this technique is controlled and accompanied by a good knowledge of the environment conditions.
Industrial applications of cathodic protection mainly concern :
buried or submerged pipelines
underground tanks, capacity interiors, in combination with passive protection
protection of vessels, buoys,
protection of port structures and offshore platforms
This technique is developing in new sectors such as reinforced or prestressed concrete overhead structures (bridge decks, piers) and offshore wind turbine structures.
PRINCIPLE OF CATHODIC PROTECTION
Corrosion of metals in contact with aqueous media (water, soil, concrete) is electrochemical in nature.In these media, the application of the cathodic protection technique is intended to reduce the polarization potential of the metal to a level where the corrosion rate of the metal is significantly reduced.The cathodic protection threshold can be determined thermodynamically.It corresponds to the immunity threshold as shown in the Pourbaix diagrams (Figures 2) corresponding to a state from which corrosion becomes theoretically impossible.
To modify the potential of the metal to be cathodic protected, an anode is used installed in the same electrolyte.Anodes can be of two types :
either anodes with a more electronegative potential than the metal to be protected (galvanic anode or sacrificial anode)
or anodes coupled to a current generator imposing a difference in potential between the two metals (imposed current method)
The choice of one system over another must be made taking into account technical comparisons (cf. Table 6) and economic criteria (design, equipment, installation, maintenance, material and energy consumption).
The purpose of the cathodic protection by sacrificial anodes is to take advantage of the effect of the galvanic couple (battery) created by the association, in the same electrolyte, of two different metals: the metal to be protected and a less noble metal that constitutes the anode.In this type of protection, the anode is consumed by dissolution by carrying the surface of the metal to be protected beyond its immunity potential.
For protection to exist, it is necessary that :
the battery flows, so that the anode is electrically connected to the metal,
the surface to be protected and the anode are all immersed in the same electrolytic environment,
the installation is adapted to the surface to be protected (dimensions, number, distribution of anodes).
Protection by sacrificial anodes does not last indefinitely.It stops with the disappearance of sacrificial material or by electrochemical blocking.The evaluation of its lifetime is estimated by calculation of anode sizing and by return of experience (from a few months to several decades).
There are several sacrificial anode alloys with different characteristics and applications.In the case of steel protection, the anodes used are based on zinc, aluminum or magnesium alloy.Studies and experience have made it possible to determine, for each of the alloys, the thresholds of permissible impurities as well as the complementary elements necessary to obtain the best performance.
AMPERE has been manufacturing these sacrificial anodes in Zinc GALVA PROCAT® or Aluminum HYDRAL 2C® alloy in France for over 25 years
Between 1995 and 2001, AMPERE took over the cathodic protection activities of the companies VIEILLE MONTAGNE for zinc alloys and PECHINEY for aluminum alloys and thus benefited from the studies and experiments of these two major industrial groups.
We set up and developed our sacrificial anode factory in the center of France. We benefit from modern and high-performance production tools, ensuring perfect regularity and excellent quality of our Zinc Galva PROCAT® or Aluminium HYDRAL 2C® alloys. Our range of sacrificial anodes allows us to supply anodes from a few grams up to more than 300 kg.
As the leading French producer of sacrificial anodes, we are a qualified and approved supplier to the major shipbuilding and maritime industries, as well as to the oil, and offshore industries, thanks to our Zinc GALVA PROCAT® and Aluminum HYDRAL 2C® alloys.